Friday, 9 February 2018

Non Aqueous Solvent

Non-Aqueous Solvent 

The substance which serves as a good solvent like water having a high ionising capacity and di-electric constant is known as non-aqueous solvent.
 Exam:- Anhydrous liquid ammonia, liquid sulphur-dioxide, anhydrous HF etc.

Note:- Liquid ammonia is one of the most extensively studied non-aqueous solvents. Due to its water like properties it is a highly useful solvent and a reaction medium for several types of organic and inorganic reactions. 


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Co-precipitation

Co-Precipitation

It is the phenomenon by which the soluble substances carried out by the insoluble precipitate.
During the precipitation of a substance, sometimes soluble substances are also carried out by it. The soluble substance is said to be co-precipitated.

Exam:- During the precipitation of BaSO4 by adding BaCl2 in K2SO4  solution, a little K2SO4 is also carried out with BaSO4. It is said to that K2SO4 is co-precipitated. It is hard to remove by washing.

                                           

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Ideal Crystal

Ideal Crystal :- 

 An ideal crystal is that which has similar unit cell containing the same lattice points throughout the whole crystal.
At absolute zero, most of the crystals have well ordered arrangement of ions. In such crystals there are no defects. Above absolute temperature, deviation takes place in regular arrangements of ions in crystals.

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Monday, 1 May 2017

Collision theory of chemical reaction

                             Collision theory    

Collision theory of chemical reaction :

According to this theory, reactants are assumed to be hard spheres, which must collide with one-another. The no. of collision per second per unit volume of the reaction mixture is known as collision frequency (Z).
       According to this theory, all the collision do not result in the product formation. The collision of reactants which results in the product formation are called as effective collision.
 The following two conditions must be satisfied for effective collision ---

1) Energy factor : The colliding particles must have energy greater than or equal to threshold energy. If they do not have such energy, they take this energy externally in the form of heat, light, electric current etc. which is called as activation energy.

2) Orientation factor or Probability factor or Steric factor :
  According to this factor, colliding particles must be properly oriented, with respect to each other, otherwise reactants bounced back and no product will form.




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Tuesday, 18 April 2017

Laws of photo electric effect

Laws of photo electric effect : The laws of photo electric effect are----

  • The number of electrons emitted per second will be directly proportional to the intensity of radiated light.
                  Number of photo electrons α intensity of incident light
                  Number of photo electrons α photo electric current
  • There is a lower limit of frequency called threshold frequency below it no emission takes place however high the intensity of the incident radiation. So that ---
                                 E > W₀ ,    ν > ν₀   and       λ <  λ₀ 
  • Above threshold frequency the maximum velocity with which electrons emerges is dependent on the frequency and not on the intensity of the radiated light.
                                    ½ mv2max  α  ν
  • The emission of photo electron is an instantaneous process. It means time difference between incidence of light and emission of photo electron is very small may be less than even 10-9 second.{no time lag}
                                                                                 https://youtu.be/O3D2belxKBs

stopping potential or cut off potential

Cut-off potential : The minimum negative potential required to just make the photo electric current of the plate is zero, defined as stopping potential.

                 Kmax = eV₀           {eV₀ = stopping potential} 


Electron volt : One electron volt is the kinetic energy gained by an electron when it is accelerated through a potential difference of one volt.
                                     1eV = qV
                                     1eV = 1.602 x 10-19  x 1

                                     [1eV = 1.602 x 10-19 ]   

                                                                                             https://youtu.be/O3D2belxKBs      

Electric field due to uniformly charged thin wire

Electric field due to uniformly charged thin wire :

Consider a long  thin wire carrying charge Q distributed uniformly over the wire. Let the linear charge density of the wire is λ. Let a point p where we have to find the electric field making an angle α with the centre. Then the electric field will be -----
                   

 
       As we know,
                               λ = dQ/dy
                              dQ = λdy    .............................(1)

                In the above triangle,
                              tanα  = y/x
                              y= x tanα   
                             dy = x sec2αdα  ..................(2)
  
              In the above triangle,
                            cosα = x/r
                             r = x  cosα  .......................(3)
           Electric field at point due to dQ ----
                            dE= dQ/4πЄ₀r2
                            dE= λdy/4πЄ₀r2         {since, dQ=λdl from eq. 1}      .................(4)
  putting the value of dy and r from equation (2) and (3) in eq. (4), we get----
                            dE =  λ x sec2α dα/4πЄ₀ x2sec2α
                            dE = λdα/4πЄ₀x 

On x-axis the electric field will be-----

                            dEx  = λdα cosα/4πЄ₀x
                             ഽdEx  = -π/2π/2λ cosαdα/4πЄ₀x
                              ഽdEx  = λ /4πЄ₀x-π/2π/2 cosαdα
                               Ex  = λ/4πЄ₀ x {[sinα]-π/2π/2}
                                Ex  = λ/4πЄ₀ x {Sinπ/2 + Sinπ/2} 
                                Ex  = 2λ/4πЄ₀ x
so the electric field in x-axis will be-
                                 Ex  = λ/2πЄ₀ x.


On the y-axis electric field will be -----

                               dEy  = λdα sinα/4πЄ₀x
                              ഽdEy  = -π/2π/2λ sinαdα/4πЄ₀x
                             ഽdEy  = λ /4πЄ₀x-π/2π/2 sinαdα
                              Ey  = λ/4πЄ₀ x {[-cosα]-π/2π/2}
                              Ey  = λ/4πЄ₀ x {cosπ/2 + cosπ/2} 
                               Ey  = 0.
so the net electric field on the y-axis will be ---
                                  Ey  = 0.
  
                                                                                                                          https://youtu.be/O3D2belxKBs